BSAU EEE 2015 Chemistry Syllabus

Category: Syllabus 14 0

BSAU EEE 2015 Chemistry Syllabus:

Inorganic Chemistry:

Atomic Structure:
Dual properties of electrons-de-Broglie relation- Heinsenberg’s uncertainty principle – Wave nature of an electron – Schrodinger wave equation (only equation, no derivation) – Eigen values and Eigen function – significance only – molecular orbital method. Application to Homo diatomic and Hetero diatomic molecules – Metallic Bond – Hybridization of atomic orbitals. Hybridization involving p and d Orbitals – Types of forces between molecules.

Periodic Classification:
Review of periodic properties – Calculation of atomic radii – calculation of ionic radii – method of determination of Ionisation potential – Factors affecting ionization potential – Method to determine the electron affinity – factors affecting EA-Various scales on electro negativity values.

P – Block elements:
Group – 13 General trends – Potash alum – Preparation, Properties and uses – Group 14 General trends – Phosphorous – Allotropes and extraction – Compound of phosphorus – Group – 16 General trends – Manufacture and properties. – Group – 17 General characteristics. Physical and chemical properties – Isolation of fluorine and its properties – Inter halogen compounds Group – 18 Inert gases – Isolation, properties and uses.

D – Block elements:
General characteristics of D – block elements – first transistion series Occurrence and principles of extraction – chromium, copper and zinc – Alloys – Second transition series – Occurrence and principles of extraction of silver – Third transition series – Compounds, Purple of Cassius.

F – Block elements:
General characteristics of F-Block elements and extraction – Comparison of Lanthanides and Actinides – Uses of lanthanides and actinides.

Coordination Compounds and Bio-Coordination Compounds:
An introduction – Terminology in coordination chemistry – IUPAC nomenclature of mononuclear coordination compounds – Isomerism in coordination compounds – Structural isomerism – Geometrical isomerism in 4 – coordinate, 6 – coordinate complexes – theories on coordination compounds – Werner’s theory (brief) – Valence bond theory – crystal field theory – Uses of coordination compounds – Bio coordination compounds. Haemoglobin and chlorophyll.

Nuclear Chemistry:
Nuclear energy nuclear fission and fusion – Radio carbon dating – Nuclear reaction in sun – Uses of radioactive isotopes.

Physical Chemistry:

Solid State II :
Types of packing in crystals – X – Ray crystal structure – Types of ionic crystals – Imperfections in solids – Properties of crystalline solids – Amorphous solids.

Thermodynamics II:
Review of I law – Need for the II of thermodynamics – spontaneous and non spontaneous processes – Entropy – Gibb’s free energy – Free energy change and chemical equilibrium – Third law of thermodynamics.

Chemical Equilibrium II:
Application of law of mass action – Le Chatlier’s principle.

Chemical Kinetics II:
First order reaction and pseudo first order reaction – Experimental determination of first order reaction – method of determining order of reaction – temperature dependence of rate constant – simple and complex reactions.

Surface Chemistry II:
Adsorption – Catalysis – Theory of catalysis – Preparation of colloids – Properties of colloids – Emulsions.

Electrochemistry I:
Conductor, insulators and semi conductors – theory of electrical conductance – theory of strong electrolytes – Faraday’s laws of electrolysis – Specific resistance, specific conductance, equivalent and molar conductance – Variation of conductance with dilution – Kohlraush’s law – Ionic product of water, pH and pOH – Buffer solutions – Uses of pH values.

Electrochemistry II:
Cells – electrodes and electrode potentials – Construction of cell and EMF –  Corrosion and its preventions – commercial production of chemicals – Fuels cells.

Organic Chemistry:

Isomerism in Organic Chemistry:
Geometrical isomerism – Conformations of cyclic  compounds – Optical isomerism – Optical activity – Chirality – Compounds containing chiral centers – D – L and R – S notation – Isomerism in benzene.

Hydroxy Derivatives:
Nomenclature of alcohols – Classification of alcohols – General methods of preparation of primary alcohols – Properties methods of distinction between three classes of alcohols 10, 20, 30 – Methods of preparation of dihydric alcohols. (glycol) – Properties – Uses – methods of preparation of trihydric alcohols – Properties – Uses – Aromatic alcohols – Methods of preparation of benzyl alcohol – Properties – Uses – phenols – Manufacture of phenols – Properties – Chemical properties – Uses of Phenols.

Ethers:
Ethers – General methods of preparation of aliphatic ethers – Properties – Uses – Aromatic ethers – Preparation of anisole – Reactions of anisole – Uses.

Carbonyl Compounds:
Nomenclature of carbonyl compounds – compounds of aldehydes and ketones – general methods of preparation of aldehydes – Properties – Uses of Aromatic aldehydes – Preparation of benzaldehyde – Properties – Uses – Ketones – general methods of preparation of aliphatic ketones (acetone) – Properties – Uses – Aromatic ketones – preparation of acetophenone – Properties of benzo – phenone – Properties.

Carboxylic Acids:
Nomenclature – Properties of aliphatic mono carboxylic acids – formic acids – properties – uses – tests for carboxylic acid – Monohydroxy mono carboxylic acids – Lactic acid – Sources – Synthesis of lactic acid – Aliphatic dicarboxylic acids – preparation of dicarboxylic acids – oxalic and succinic acids – Properties – Strengths of carboxylic acids – Aromatic acids – Preparation of benzoic acids – Preparation of acid chloride – acetyl chloride – Preparation – properties – Uses – Preparation of acetamide – properties – preparation of acetic anhydride – properties – preparation of esters methyl acetate – properties.

Organic nitrogen Compounds:
Aliphatic nitro compounds – preparation of aliphatic nitroalkanes – properties – uses – aromatic nitro compounds – preparation – properties – uses – distinction between aliphatic and aromatic nitro compounds – Amines – Aliphatic amines – General methods of preparation – Properties – Distinction between 10, 20, and 30 amines – Aromatic amines – Synthesis of benzylamine – Properties – Aniline –  preparation – Properties – uses – distinction between aliphatic and aromatic amines – Aliphatic nitriles – preparation – properties – Uses – Diazonium salts – preparation of benzene diazoniumchloride – properties.

Biomolecules:
Carbohydrates – structural eludication – Disaccharides and polysaccharides – Proteins – Amino acids – structure of proteins – nucleic acids – Lipids.

Chemistry in Action:
Medicinal chemistry – Drug abuse – Dyes – classification and uses – Cosmetics – creams, perfumes, talcum powder and deodorants – chemicals in food – preservatives artificial sweetening agents, antioxidants and edible colors – Insect repellent – pheromones and sex attractants – rocket fuels – types of polymers, preparation and uses.

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